Grignard reagents add to ketonirrones in a nonpolar solvent to afford N,N-dialkylhydroxylamines in good yieids and with liiule compeling proton Paqfer. ## Deoxygenalion of the crude hydroxylatrSnes with carbon disulfide then compleres an eficient general synthetic route to hindered set-alkyl-lert-a
✦ LIBER ✦
An Improved Synthesis of Ketonitrones
✍ Scribed by Franco, S.; Merchán, F. L.; Merino, P.; Tejero, T.
- Book ID
- 120477361
- Publisher
- Taylor and Francis Group
- Year
- 1995
- Tongue
- English
- Weight
- 404 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0039-7911
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Synthesis of hindered secondary amines v
✍
Martin A. Schwartz; Xiufeng Hu
📂
Article
📅
1992
🏛
Elsevier Science
🌐
French
⚖ 323 KB
An improved synthesis of tetramesitylpor
✍
Richard W. Wagner; David S. Lawrence; Jonathan S. Lindsey
📂
Article
📅
1987
🏛
Elsevier Science
🌐
French
⚖ 151 KB
We report a simple two-step one-flask procedure for the synthesis of tetramesitylporphyrin in 29% yield. Pyrrole and mesitaldehyde react at room temperature to form tetramesitylporphyrinogen. The addition of an oxidant yields the porphyrin. Macrocycle formation and oxidative aromatization are thus p
An improved synthesis of cyclopropanols
✍
Gary N. Barber; R.A. Olofson
📂
Article
📅
1976
🏛
Elsevier Science
🌐
French
⚖ 258 KB
An improved synthesis of pavinanes
✍
David A. Walsh; Robert E. Lyle
📂
Article
📅
1973
🏛
Elsevier Science
🌐
French
⚖ 107 KB
An improved synthesis of corrole
✍
Saburo Neya; Kaori Ohyama; Noriaki Funasaki
📂
Article
📅
1997
🏛
Elsevier Science
🌐
French
⚖ 271 KB
An improved synthesis of norcocaine
✍
V. I. Stenberg; N. K. Narain; S. P. Singh; S. S. Parmar
📂
Article
📅
1976
🏛
Journal of Heterocyclic Chemistry
🌐
English
⚖ 92 KB