An Improved Protocol for the Ruthenium(pybox)-Catalyzed Asymmetric Alkene Epoxidation.
β Scribed by Man Kin Tse; Santosh Bhor; Markus Klawonn; Christian Doebler; Matthias Beller
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 156 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A considerable improvement is reported in the ironβcatalyzed ringβexpansion reactions of epoxides generating tetrahydrofuran derivatives by formal insertion of an alkene. Optimization of the catalyst system revealed that a preformed [Fe(salen)] complex minimizes the formation of polymer
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