## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
An improved method for the generation of imines and enamides. Application to the synthesis of 3-arylisoquinoline derivatives
✍ Scribed by Nuria Sotomayor; Teresa Vicente; Esther Domínguez; Esther Lete; María-Jesús Villa
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 984 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
The one-not oreoaration of hindered 1%diawlethvlamines 3 and 4 and etbvlenenamides 5 is achieved vfa . . sodium cyanoborohydride reduction and acylation of thedeox;benzoin imines 2, respectively. A new methodology for the synthesis of 3arylisoquinolinium salts by the Bischler-Napieralski reaction of 1,2-diarylethylenenamides and their transformation into 12-methyl substituted benzo[c]phenanthridines has been developed.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Abstmct: Reaction qfaromatic aldehydes and certain a&waturated carLmy compounds w&h 1,2&s(chlorodinwthyMlyl)ethane and zinc leaa to products of sytnmtrical dicarbmyi coupling.
## Hydrogenation O 0220 An Efficient Method for the Synthesis of Enantiopure Phosphine-Imidazoline Ligands: Application to the Ir-Catalyzed Hydrogenation of Imines. -Novel arylimidazolines (I), obtained efficiently via reaction of aryldithioesters with chiral diamines, are used as ligands in the a