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An improved method for the direct computation of diatomic centrifugal distortion constants

✍ Scribed by Joel Tellinghuisen

Book ID
107802392
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
528 KB
Volume
122
Category
Article
ISSN
0022-2852

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For a given vibrational level v the problem of the centrifugal distortion constants (CDC) for a given electronic state of a diatomic molecule is considered. Within the perturbation theory approach, a CDC of order n is given by e. = R n-I (cko qb.\_ 1) -~m=O em (dpoqb.-m). Once the vibrational energy