An improved method for the catalytic preparation of t-butyl esters of carboxylic and fatty acids
β Scribed by Harold Wiener; Chaim Gilon
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 461 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
hydroperoxides and t-butyl peroxides have been prepared -some of them for the first time -by the application of known procedures.
2,2-Dimcthoxypropane, methanol and a catalytic amount of HCI selectively esterify aliphatic carboxylic acids, in the presence of aromatic carboxylic acids, at room temperature and in high yields.
## Swnmary: T-butyl 2,2,2-trichloroaceiimi&e (l), reaa?ly prepared by addition of t-butawl to trichloroacetonitrile, is an efficient reagent for the preparation of t-butyl ethers and esters in the presence of a catalytic amount of boron trifhon& etherate. Traditional methods for the preparation of