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An Improved Convergent Strategy for the Synthesis of Oligoprenols

✍ Scribed by Xiong-Jie Yu; Hao Zhang; Fang-Jun Xiong; Xu-Xiang Chen; Fen-Er Chen

Publisher
John Wiley and Sons
Year
2008
Tongue
German
Weight
186 KB
Volume
91
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

A practical and highly regio‐ and stereoselective synthesis of oligoprenols starting from commercially available geraniol is described. The convergent synthetic strategy features the iterative allyl‐allyl coupling of monomers easily derived from geraniol that contain one reacting terminal functional group and the repetitive reductive elimination of the p‐toluenesulfonyl (Ts) groups.

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