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An improved acylation of phenol over modified ZSM-5 catalysts

✍ Scribed by Y.V. Subba Rao; S.J. Kulkarni; M. Subrahmanyam; A.V. Rama Rao

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 273 KB
Volume: 133
Category: Article
ISSN: 0926-860X
DOI: 10.1016/0926-860x(95)00212-x

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✦ Synopsis

The acylation of phenol with acetic anhydride was carried out over different modified ZSM-5 catalysts. Co, Cu, and Ce showed a promoting effect. The best temperature and weight hourly space velocity for this reaction were found to be 250°C and 0.5 h-~, respectively. ZSM-5(30) was found to be a better catalyst than ZSM-5(150) and in the acylation of phenol. A plausible reaction mechanism is also discussed.

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