An FTIR study on the structure of the oxygen-evolving Mn-cluster of Photosystem II in different spin forms of the S2state
β Scribed by Kouichi Onoda; Hiroyuki Mino; Yorinao Inoue; Takumi Noguchi
- Book ID
- 110234618
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 208 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0166-8595
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Electron paramagnetic resonance (EPR) spectroscopy and 02 evolution assays were performed on photosystem II (PSII) membranes which had been treated with 1 M CaC12 to release the 17, 23 and 33 kilodalton (kDa) extrinsic polypeptides. Manganese was not released from PSII membranes by this treatment as
Metal and ligand hyperfine couplings of a previously suggested, energetically feasible Mn(4)Ca model cluster (SG2009(-1)) for the S(2) state of the oxygen-evolving complex (OEC) of photosystem II (PSII) have been studied by broken-symmetry density functional methods and compared with other suggested