𝔖 Bobbio Scriptorium
✦   LIBER   ✦

An ftir study of the reaction between nitrogen dioxide and alcohols

✍ Scribed by H. Niki; P. D. Maker; C. M. Savage; L. P. Breitenbach

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
440 KB
Volume
14
Category
Article
ISSN
0538-8066

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✦ Synopsis

The reaction 2N02 + ROH = RON0 + HN03 (R = CH3 or CzHb) has been studied using the FTIR method at reactant pressures from 0.1 to 1.0 torr at 25Β°C. The termolecular rate constant for the forward reaction was determined to be (5.7 f 0.6) X cm6/molec2.s for CH30H and (5.

The corresponding equilibrium constants were measured as 1.36 f 0.06 and 0.550 f 0.025 torr-I, respectively. These results are consistent with those of a previous study based on the NO2 decay measurements a t reactant pressures from 1 to 10 torr.

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