The kinetics and mechansim for the NO,-initiated oxidation of tetramethyl ethylene ITME) have been studied using the FTIR spectroscopic method in mixtures containing NO, and TME (0.1-1.0 Torr) and N,-02 (700 Tori-) at 298 t 2 K. While TME decayed according to -d[TME]/dt = hOb,iNOLl [TME], NOz exhibi
An FTIR study of mechanisms for the HO radical initiated oxidation of C2H4 in the presence of NO: detection of glycolaldehyde
β Scribed by H. Niki; P.D. Maker; C.M. Savage; L.P. Breitenbach
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 410 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0009-2614
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The photooxidation of acrylonitrile, methacylonitrile, and allylcyanide in the presence of NO was studied in parts per million concentration using the long-path Fourier transform IR spectroscopic method. The stoichiometry of the OH radical initiated oxidatiy? of methacrylonitrile was established as
The reaction OH + C2H4 was investigated in the presence of NO and 0, at 760 ? 5 Torr total pressure and 298 t 2 K. OH radicals were generated by excimer laser photolysis of H,O, at 248 nm and were detected by laser-induced fluorescence. OH concentration-time profiles, which were measured for differe