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An Extraordinarily Violent Molecular Dissociation: The Unprecedented Kinetic Energy Release in the Decomposition of HONF+, a Singly Charged Metastable Ion

✍ Scribed by Prof. Dr. Fulvio Cacace; Dr. Felice Grandinetti; Dr. Federico Pepi


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
352 KB
Volume
33
Category
Article
ISSN
0044-8249

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✦ Synopsis


The mass spectrum was obtained for positive and negative secondary ions in a range of 0-100. 5. The degree of substitution of the gel was monitored by adding 0.05.-0.25 pCimL-' n-[l-'4C]-butanethiol (NEN) [14] or n-[I-"TI-butylamine (Hoechst AG) to the coupling mixture (as described in ref. [22]). The amount of coupled alkyl residues was determined by liquid scintillation counting [22] after acid hydrolysis of the n-[l-'4C]-butyl-labeled agarose (colorless hydrolysate). Analyses were done in triplicate.