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An extension of the Kamlet?Taft basicity scale of solvents

✍ Scribed by Krygowski, Tadeusz M.; Milczarek, Elizbieta; Wrona, Piotr K.

Book ID: 121427725
Publisher: Royal Society of Chemistry
Year: 1980
Tongue: English
Weight: 644 KB
Volume: 11
Category: Article
ISSN: 1472-779X
DOI: 10.1039/P29800001563

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Correlation of thione-to-thiol rearrange

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The thione-to-thiol rearrangement rates for O-(2-alkenyl) (la-c), O-(l-cyclopmpylethyl) (ld) and O-(2-methylthioethyl) (le) S-methyl xanthates were analyzed by the Kamlet-Taft equation. The results indicate that solvent polarity and solvent hydrogen-bond donation ability (acidity) are operative in