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An Exploration of the Potential of [4 + 2] Cycloadditions of α-Pyrones with Indenones for the Synthesis of the Norditerpenoid Tropone, Harringtonolide.

✍ Scribed by Lewis N. Mander; Timothy P. O'Sullivan


Book ID
101954621
Publisher
John Wiley and Sons
Year
2003
Weight
75 KB
Volume
34
Category
Article
ISSN
0931-7597

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Diels–Alder cycloadditions of 3,5-dibrom
✍ Cheon-Gyu Cho; Yong-Woo Kim; Won-Kyum Kim 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 56 KB

Dibromo-2-pyrone underwent facile Diels-Alder [4+2] cycloadditions with cycloalkenyl silyl ethers to provide a series of tricyclolactones, with good to excellent chemical yields and stereoselectivity. The resulting cycloadducts could be readily converted into the corresponding bicarbocycles upon sel