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An experimental study of the excited state rotational population of OH in flames using laser induced fluorescence

✍ Scribed by G. Zizak; J.A. Lanauze; J.D. Winefordner


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
672 KB
Volume
65
Category
Article
ISSN
0010-2180

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✦ Synopsis


Rotationally resolved fluorescence spectra of OH in three different flames and for different excitation levels have been measured and analyzed. The extracted population distributions have been treated with a simple model based on a steady state rate approach. Global parameters such as the ratio of rotational energy transfer and "average" quenching and thermalization degree have been measured. For an exact analysis of the relative population of individual levels, knowledge of the state-to-state cross sections for collisional transfer and numerical programs are needed.