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An experimental investigation of the effect of prepolymer molecular weight and stoichiometry on thermal and tensile properties of epoxy resins

✍ Scribed by T. P. Skourlis; R. L. McCullough


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
816 KB
Volume
62
Category
Article
ISSN
0021-8995

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✦ Synopsis


An experimental study was undertaken to investigate the thermomechanical properties of a certain epoxy/amine configuration. The basic structure of all the epoxies was the same-DGEBA-and the curing agent used was PACM 20. By varying the epoxy prepolymer molecular weight and the stoichiometry between epoxy and amine, a range of different epoxy networks were produced. Glass transition temperatures were evaluated by using differential scanning calorimetry (DSC). Modulus values as well as an alternative T, determination were provided by dynamic mechanical analysis (DMA). Coefficients of thermal expansion were obtained from thermomechanical analysis (TMA). The tensile tests conducted a t room and elevated temperatures provided additional modulus data along with the yield point, tensile strength, and elongation a t break data. Property vs. stoichiometry curves exhibited a maximum for the glass transition temperature and the over the T, modulus a t the stoichiometric point. On the other hand, the under Tg modulus showed a minimum a t the stoichiometric point. The results of the yield strength show remarkable similarity with the results of the modulus. Strength and elongation a t break do not show clear trends, but a much different behavior is exhibited between room and elevated temperatures.


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