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An experimental investigation of the double ionization of hydrogen sulphide to triplet electronic states of the dication

✍ Scribed by S.R. Andrews; F.M. Harris

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
235 KB
Volume
253
Category
Article
ISSN
0009-2614

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✦ Synopsis

A double-charge-transfer spectroscopy study of hydrogen sulphide has been carried out, and six double-ionization energies to various electronic states of H2 $2Γ· measured. Because of the conservation of spin multiplicity in the double-charge-transfer reactions which are central to this type of spectroscopy, and the use of OH + as the projectile ion, triplet states of H2S 2+ were populated. This was confirmed by the good agreement between the measured double-ionization energies and published calculated values for transitions to triplet states of H2S 2+.

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