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An Experimental and Theoretical Study of Stereoselectivity of Furan−Maleic Anhydride and Furan−Maleimide Diels−Alder Reactions

✍ Scribed by Rulíšek, Lubomír; Šebek, Pavel; Havlas, Zdeněk; Hrabal, Richard; Čapek, Pavel; Svatoš, Aleš

Book ID
115537698
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
307 KB
Volume
70
Category
Article
ISSN
0022-3263

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✍ José M. Fraile; José I. García; María A. Gómez; Antonio de la Hoz; José A. Mayor 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 401 KB

Silica-supported Lewis acids are good catalysts for Diels-Alder reactions between furan and acrylonitrile and methyl acrylate at room temperature. When 2,5-dimethylfuran is used as the diene, yields of the Diels-Alder adducts with methyl acrylate are lower, due in part to the appearance of aromatiza