An Experimental and Theoretical Study of Spin−Spin Coupling in Chlorosilanes
✍ Scribed by Thorshaug, Knut; Swang, Ole; Dahl, Ivar M.; Olafsen, Anja
- Book ID
- 127110772
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 148 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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An experimental study of the e †ects of intramolecular electric Ðelds on 1J(C,H) coupling constants involving a formyl proton in a series of 5-X-salicylaldehydes is reported. The particularly large electric Ðeld component along the bond, calculated for leads to a measured substituent e †ect of 7.36