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An Experimental and Computational Study of Stereoselectivity and Reactivity in Lewis Acid Promoted Lithiation-Substitution of Tertiary Amines

✍ Scribed by Kessar, Satinder V.; Singh, Paramjit; Singh, Kamal Nain; Venugopalan, P.; Kaur, Amarjit; Bharatam, Prasad V.; Sharma, Arvind K.


Book ID
121431081
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
62 KB
Volume
129
Category
Article
ISSN
0002-7863

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endo-exo Selectivity in Diels-Alder cycloadditions of several o-quinodimethanes (1-4) with acrylonitrile, 2-(5H)-furanone and N-methylmaleimide has been investigated in acetonitrile solution. Transition structures of the cycloaddition of the parent o-QDM (1), (E,E)-1,8-dimethyl-o-QDM (2), isoindene