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AN EXPEDITIOUS SYNTHESIS OF 3-NITROPROPIONIC ACID AND ITS ETHYL AND METHYL ESTERS

โœ Scribed by Silva, Paulo C.; Costa, Jeronimo S.; Pereira, Vera L. P.


Book ID
118017929
Publisher
Taylor and Francis Group
Year
2001
Tongue
English
Weight
115 KB
Volume
31
Category
Article
ISSN
0039-7911

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An Expeditious Synthesis of Methyl Jasmo
โœ Christian Chapuis; Carole Cantatore; Jean-Yves deโ€…Saintโ€…Laumer ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 83 KB

## Abstract We present an efficient threeโ€step, twoโ€pot synthesis of methyl jasmonate (__trans__โ€1) based on __Dielsโ€“Alder__ cycloaddition of cyclopentโ€2โ€enone (2) and chloroprene (=โ€‰2โ€chlorobutaโ€1,3โ€diene; 3d) in either CHCl~3~ or CH~2~Cl~2~, catalyzed by SnCl~4~ (0.2โ€…molโ€equiv.) at 20ยฐ (75% yield