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An expeditious solvent-free route to ionic liquids using microwaves

✍ Scribed by Varma, Rajender S.; Namboodiri, Vasudevan V.

Book ID
118018629
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
54 KB
Volume
7
Category
Article
ISSN
1359-7345

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A fast and efficient protocol is proposed for the synthesis of diaryl sulfoxides in the ionic liquid 1-butyl-3-methylimidazolium chloroaluminate, [bmim]Clβ€’AlCl 3 , N=0.67, by employing arenes and thionyl chloride. The ionic liquid plays a dual role of Lewis acid catalyst and solvent, under ambient c