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An expeditious regioselective synthesis of [60]fullerene e,e,e tris-adduct building blocks

✍ Scribed by Sigwalt, David; Schillinger, Franck; Guerra, Sebastiano; Holler, Michel; Berville, Mathilde; Nierengarten, Jean-François


Book ID
120508197
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
734 KB
Volume
54
Category
Article
ISSN
0040-4039

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The Orthogonal (e,e,e)-Tris-Adduct of 9,
✍ Alvaro Duarte-Ruiz; Klaus Wurst; Bernhard Kräutler 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 German ⚖ 412 KB 👁 1 views

Tris (9',10'-dimethyl[9,10]ethanoanthracene [11',12': 1,9;11'',12'': 16,17;11''',12''': 30,31]) [5,6]fullerene C 60 , the orthogonal (e,e,e)-tris-adduct of C 60 and 9,10-dimethylanthracene, was obtained from [4 þ 2]cycloaddition (Diels -Alder reaction) at room temperature. The thermally unstable ora