An evaluation of the Noyori system “in reverse”: Thermodynamic and kinetic parameters of secondary alcohol transfer dehydrogenation catalyzed by [(η6-1-iPr-4-Me-C6H4)Ru(HN-CR′R″-CR′R″NTs)], R′ = H, Me; Ph, R″ = H, Me

Regio- and enantioselectivity in the alk

Regio- and enantioselectivity in the alkylation and etherification reactions of cinnamyl allylic derivatives catalyzed by [(η5-C5R5)Ru(N–N*)(NCCH3)]PF6 (R = H, Me) complexes containing N–N* bulky chiral ligands of different rigidity and flexibility

✍ Maria Saporita; Giovanni Bottari; Giuseppe Bruno; Dario Drommi; Felice Faraone 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 206 KB

a b s t r a c t [( 5 -C 5 R 5 )Ru(N-N\*)(NCMe)]PF 6 (R = H, N-N\* = (Sa)-1, 5; (Sa)-2, 6; (R,R)-3, 7; (R,R)-4; 8; R = Me, N-N\* = (Sa)-1, 9) complexes containing N-N\* bulky chiral ligands of different rigidity and flexibility were synthesized by reacting the precursor [( 5 -C 5 R 5 )Ru(NCMe) 3 ]PF

An evaluation of the Noyori system “in reverse”: Thermodynamic and kinetic parameters of secondary alcohol transfer dehydrogenation catalyzed by [(η6-1-iPr-4-Me-C6H4)Ru(HN-CR′R″-CR′R″NTs)], R′&#xa0;=&#xa0;H, Me; Ph, R″&#xa0;=&#xa0;H, Me

An evaluation of the Noyori system “in reverse”: Thermodynamic and kinetic parameters of secondary alcohol transfer dehydrogenation catalyzed by [(η6-1-iPr-4-Me-C6H4)Ru(HN-CR′R″-CR′R″NTs)], R′ = H, Me; Ph, R″ = H, Me