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An ester migration in the rearrangement of a diels?alder adduct of a furan and a phenyl migration in the rearrangement of methyl 3,3,5-triphenylpyrazole-4-carboxylate

✍ Scribed by Abbott, Patrick J.; Acheson, R. Morrin; Flowerday, Rowena F.; Brown, Geoffrey W.


Book ID
121423021
Publisher
Royal Society of Chemistry
Year
1974
Weight
315 KB
Volume
0
Category
Article
ISSN
1472-7781

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Ketene Formation or Phenyl-Group Migrati
✍ Evangelos G. Bakalbassis; Spyros Spyroudis; Constantinos A. Tsipis πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 439 KB

## Abstract Phenyliodonium ylides of hydroxyquinones easily undergo intramolecular rearrangements associated with phenyl‐group migration or ketene formation under ambient conditions. The mechanism of the two rival potential reaction paths was explored by electronic structure calculation techniques