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An ESR study of radicals in CaCO3 produced by 1.6 MeV He+- and γ-irradiation

✍ Scribed by Kohno Hideo; Yamanaka Chihiro; Ikeya Motoji; Ikeda Sumiko; Horino Yuji

Book ID
113286175
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
326 KB
Volume
91
Category
Article
ISSN
0168-583X

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Studies on Radical Cations I. Molecular
Studies on Radical Cations I. Molecular and electronic structure of [3]radialene cation produced by γ-irradiation in condensed phase
✍ Thomas Bally; Edwin Haselbach; Zuzana Lanyiova; Peter Baertschi 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 780 KB

## Abstract γ‐Irradiation of tris (methylidene)‐cyclopropane (‘[3]radialene’) **1** in a rigid electron scavenging matrix (butylchoride/i‐pentane, 1:1) at 77 K leads to formation of its molecular cation **1**^+^. Slight softening of the matrix by a temperature increase of 3–5 K results in formation