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An Ene-type Reaction of Thionyl Chloride with Linear Isoprenoids

โœ Scribed by Vladimir A. Dragan; Alexander M. Moiseenkov

Book ID
111729419
Publisher
Royal Society of Chemistry
Year
1992
Tongue
English
Weight
538 KB
Volume
2
Category
Article
ISSN
0959-9436

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An electrochemical chlorinative ene-type
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โœ Sigeru Torii; Kenji Uneyama; Toshiyuki Nakai; Tsuneo Yasuda ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

The chlorinative ene-type reaction of isoprenoids ( 5 -2 ) has been performed by electrolysis in CH2C12-H2O-NaCl system. The reaction provides useful allylic chlorides 2 for terpene synthesis in high yields and is affected strikingly by the nature of halide ions and solvents. dl-Theaspirane ZL was