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An Enantioselective Strategy to Macrocyclic Bisindolylmaleimides. An Efficient Formal Synthesis of LY 333531

✍ Scribed by Trost, Barry M.; Tang, Weiping

Book ID
120379028
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
90 KB
Volume
3
Category
Article
ISSN
1523-7060

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An enantioselective synthesis of intermediates in syntheses of thienamycin (15) and epithienamycin-C (16) is described. Several years ago we reported that N-trimethylsilyl imines react with ester enolates to afford l-unsubstituted-B-lactams. 1 We also showed that ethyl B-hydroxybutyrate would serve