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An Empirical Correlation between Secondary Structure Content and Averaged Chemical Shifts in Proteins

โœ Scribed by Sibley, Anaika B.; Cosman, Monique; Krishnan, V.V.


Book ID
118515679
Publisher
Biophysical Society
Year
2003
Tongue
English
Weight
100 KB
Volume
84
Category
Article
ISSN
0006-3495

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An empirical correlation between the peptide ~SN chemical shift, 6~SNi, and the backbone torsion angles t~i , gti\_ 1 is reported. By using two-dimensional shielding surfaces A(l~i,/l/i\_l) , it is possible in many cases to make reasonably accurate predictions of lSN chemical shifts for a given stru