𝔖 Bobbio Scriptorium
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an elimination reaction with kinetics characteristic of the E1cB mechanism

✍ Scribed by Crowell, Thomas I.; Kemp, Robert T.; Lutz, Robert E.; Wall, Arthur A.

Book ID
120490253
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
750 KB
Volume
90
Category
Article
ISSN
0002-7863

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Dynamics Effects on an E2/E1cb Borderlin
Dynamics Effects on an E2/E1cb Borderline Mechanism: Unimolecular Elimination of 2-Aryl-3-chloro-2-R-propanols
✍ Shuhei Itoh; Prof. Hiroshi Yamataka πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 714 KB

## Abstract The mechanistic dichotomy between concerted E2 and stepwise E1cb of the base‐promoted elimination of 2‐aryl‐3‐chloro‐2‐__R__‐propanols was examined computationally at the HF, M05‐2X, and MP2 levels of theory. Optimizations of transition states (TSs) and reaction intermediates, and intri