An elevated temperature X-ray study of synthetic disordered Na-K alkali feldspars
β Scribed by C. M. B. Henderson
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 844 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0010-7999
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β¦ Synopsis
The temperature dependence of cell parameters for three disordered, synthetic alkali feldspars (Or19 , Or3s , and Orlo0) has been determined up to 1,000 ~ C. The samples show no change in composition or degree of Si-A1 disorder during the experiments. The triclinic-monoclinic inversion in the sample of composition Or19 occurs at 560~176 C and is accompanied by changes in the rates of expansion of a, b and c; the rate for a increases and those for b and c decrease above the inversion. The b and c parameters in Or100 show small decreases with increasing temperature and this may be due to thermal motion effects causing a contraction of cell directions that are fully expanded at room temperature. Calculation of the thermal expansion ellipsoids for the monoclinic phases shows that the major expansion coefficients (el) for all three samples are more than an order of magnitude greater than the intermediate (c~z) and minor (~3) coefficients. Thus the thermal expansion of these phases is dominated by that of c~1 which makes an angle of 22_+4 ~ with +a; this orientation is parallel to that of the short M-OA2 bonds. The thermal expansion mechanism for monoclinic, disordered alkali feldspars may involve tilting within the framework releasing compression along this direction and allowing the M-OA2 bonds to show high expansion rates. The stretching of the crankshaft units, which are parallel to a, may only play a subordinate role in controlling the expansion of the feldspar framework.
π SIMILAR VOLUMES
Synthetic almandine garnet, Fe3A12Si3012, has been studied by temperature -dependent single crystal X-ray diffraction and 57Fe M6ssbauer spectroscopy. The Fe 2+ doublet in almandine is characterized by a small asymmetry between the high and low-velocity peaks that decreases in magnitude with decreas