An electron spin resonance and voltammetric investigation of some 2-mono-and 2,4-di-substituted pyridinyl radicals
β Scribed by Greci, Lucedio; Alberti, Angelo; Carelli, Italo; Trazza, Antonio; Casini, Antonio
- Book ID
- 111912955
- Publisher
- Royal Society of Chemistry
- Year
- 1984
- Tongue
- English
- Weight
- 686 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1472-779X
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Voltammetric studies on mesoionic 1,2,3-oxa-and -thiadiazoles conΓrmed that the former may be reduced irreversibly at potentials between [1.48 and [2.12 V vs. Fc/Fc`in acetonitrile at a scan rate of 200 mV s~1, whereas the latter are reduced reversibly under the same conditions. The corresponding an
## Abstract Further information has been obtained on the electronic structure of 1,3,2βdithiazolβ2βyl radicals. The structure has been well characterized previously except for positions 4 and 5 in the equation image ring. We have obtained solution and powder ESR spectra of radicals substituted wi