An Electrochemical Synthesis of a Bicyclobutane
✍ Scribed by Vellturo, Anthony F.; Griffin, Gary W.
- Book ID
- 125935358
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 256 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Diazoketones are widely used as precursors in the preparation of various kinds of ring-systems by reaction with unsaturated substratesI. The reaction of diazoketones with electron-poor alkenes yields pyrazolines'; or, in case of preliminary loss of nitrogen, the corresponding keto-
## Abstract Trimethyl bicyclobutane‐1,2,2‐tricarboxylate (**2**) was synthesized by a facile five‐step route, beginning with the ferric chloride‐catalyzed addition of chloroform to methyl acrylate to give methyl 2,4,4‐trichlorobutyrate (**3**). Replacement of the 2‐chloro group by iodide was follow