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An electrochemical investigation of the interaction between the superoxide ion and cations of group 2a in aqueous solutions

✍ Scribed by Emanuele Argese; Emilio F. Orsega; Stefano Enzo; Paolo Ugo; Adelio Rigo


Publisher
Elsevier Science
Year
1988
Weight
544 KB
Volume
246
Category
Article
ISSN
0022-0728

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## Abstract Absorption spectra of the superoxide ion have been studied in dimethylformamide (DMF) and acetonitrile (AN). It was found that the superoxide ion existed in equilibrium with an ion pair in AN (__K__~eq~ = 20__M__^βˆ’1^, Bu~4~N^+^ is the cation) and as β€œfree” (solvated) ion in DMF. The add