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An efficient α-hydroxylation of carbonyls using the HOF•CH3CN complex

✍ Scribed by Sharon Dayan; Yifat Bareket; Shlomo Rozen


Book ID
104209085
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
385 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis


The complex HOF°CH3CN, made directly from fluorine and aqueous acetonitrile, was used for oc-hydroxylation of various ketones, esters and acids via their trimethyl silyl enol ethers. The reaction is usually complete in a few minutes at room temperature or below and has high yields.


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ChemInform Abstract: An Efficient α-Hydr
✍ Sharon Dayan; Yifa Bareket; Shlomo Rozen 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

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