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An Efficient Total Synthesis of Pedunculagin by Using a Twofold Intramolecular Double Esterification Strategy

✍ Scribed by Karamali Khanbabaee; Mathias Großer

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 115 KB
Volume: 2003
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200300006

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✦ Synopsis

Abstract

The total synthesis of naturally occurring pedunculagin (1) was achieved by the twofold intramolecular double esterification of enantiomerically pure (S)‐hexabenzyloxydiphenic acid (4) with the D‐glucose‐derived sugar 2 as the key step. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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