An efficient synthetic approach to novel nickel(II) 2-benzazolo-5,10,15,20-tetraphenylporphyrins

✍ Scribed by Satyasheel Sharma; Mahendra Nath

• Book ID: 102344192
• Publisher: Journal of Heterocyclic Chemistry
• Year: 2011
• Tongue: English
• Weight: 224 KB
• Volume: 49
• Category: Article
• ISSN: 0022-152X
• DOI: 10.1002/jhet.664

✦ Synopsis

Abstract

A simple and efficient synthesis of nickel(II) 2‐benzazolo‐5,10,15,20‐tetraphenylporphyrins from nickel(II) 2‐formyl‐5,10,15,20‐tetraphenylporphyrin and o‐arylenediamines, o‐aminophenols or o‐aminothiophenol in 1,2‐dichlorobenzene is described. A diverse range of novel β‐substituted azoloporphyrins has been successfully synthesized in good yields and their structures are confirmed on the basis of spectral data. J. Heterocyclic Chem., (2012).