An Efficient Synthesis of Versatile Terpyridine Analogues for Cyclometalated Luminescent Cyclodextrins. -Derivative (IIIc) is transformed to the bromide (IV) for direct attachment to mono-6-hydroxy permethylated Ξ²-cyclodextrin.
An efficient synthesis of versatile terpyridine analogues for cyclometallated luminescent cyclodextrins
β Scribed by Murielle Chavarot; Zoe Pikramenou
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 194 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
An efficient synthetic method for preparing functionalised terpyridyi analogues based on Negishi's zinc coupling is developed. These ligands form cyclometallated complexes; attaching them to cyclodextrins allows preparation of luminescent cyciometallated ruthenium cyclodextrins for the assembly of photoaetive units via non-covalent interactions.
π SIMILAR VOLUMES
2,6-Dibromopyridine N-oxide and 4-nitro-2,6-dibromopyridine N-oxide were treated with tributyl(pyridin-2-yl)stannane under the conditions of the Stille coupling reaction. Derivatives of 2,2Π-bipyridine 1-oxides as well as 2,2Π:6Π,2ΠΠ-terpyridine 1Π-oxides were synthesised. Oxidation of 2,2Π:6Π,2ΠΠ-t
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