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An efficient synthesis of pyridine containing triaza-macrocyclic triacetate ligand and luminescence properties of its europium(III) complex

✍ Scribed by Jean-Michel Siaugue; Fabienne Segat-Dioury; Alain Favre-Réguillon; Charles Madic; Jacques Foos; Alain Guy

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
104 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of diethylenetriamine with 2-nitrobenzenesulfonyl chloride leads to an activated and protected compound that could be cyclized to N-protected aza-macrocycle. After a smooth deprotection step, the macrocycle was alkylated with chloroacetic acid leading to the pyridine containing triaza-macrocycle 1 in good yield. The luminescence properties of its Eu 3+ complex were examined in aqueous solution.

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