An Efficient Synthesis of Organic Carbonates using Nanocrystalline Magnesium Oxide
✍ Scribed by M. Lakshmi Kantam; Ujjwal Pal; B. Sreedhar; B. M. Choudary
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 155 KB
- Volume
- 349
- Category
- Article
- ISSN
- 1615-4150
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✦ Synopsis
Abstract
An efficient and selective synthesis of organic carbonates using nanocrystalline magnesium oxide has been realized by the direct condensation of alcohols and diethyl carbonate. The catalyst is quantitatively recovered by simple centrifugation and can be reused for four cycles with almost consistent activity.
📜 SIMILAR VOLUMES
## Abstract Nanocrystalline MgO is an effective catalyst for the Mannich‐type reaction of alkyl, aryl, and heterocyclic N‐sulfonyl aldimines with sulfonium salts to afford the title compounds with moderate diastereoselectivities.
## Abstract An efficient, mild and selective synthesis of aromatic and aliphatic amines from the corresponding nitro compounds has been realized by using a ligand‐free heterogeneous nanocrystalline magnesium oxide‐stabilized palladium(0) catalyst, employing molecular hydrogen as the reductant. The