An Efficient Synthesis of N-Methyl Amino Acids by Way of Intermediate 5-Oxazolidinones.
β Scribed by Luigi Aurelio; John S. Box; Robert T. C. Brownlee; Andrew B. Hughes; Marianne M. Sleebs
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 257 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
N-(Ξ±-Stannylalkyl) oxazolidinones can be obtained as a mixture of diastereomers in three steps from aldehydes with yields dependent on the R group of R-CHO. They can be transformed by a tin-lithium exchange to N-(Ξ±-lithioalkyl)oxazolidinones which equilibrate rapidly to one diastereomer. These comp
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