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An Efficient Synthesis of Chiral Nonracemic Diamines: Application in Asymmetric Synthesis

✍ Scribed by Parthasarathy Saravanan; Vinod K Singh

Book ID
108386409
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
514 KB
Volume
39
Category
Article
ISSN
0040-4039

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Enantiomerically pure (S)-and (R)-isopropyl alkenylmethylphosphinates were obtained from the reaction of (R)-and (S)-isopropyl methylphosphinates, respectively, with alkenyl bromides via palladium-catalyzed formation of carbon-phosphorus bond. Optically active alkenylalkylphosphinates are largely un