An Efficient Route to Macromonomers via ATRP and Click Chemistry
✍ Scribed by Vogt, Andrew P.; Sumerlin, Brent S.
- Book ID
- 118235273
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 131 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
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## Abstract PS grafted silica nanoparticles have been prepared by a tandem process that simultaneously employs RAFT polymerization and click chemistry. In a single pot procedure, azide‐modified silica, an alkyne functionalized RAFT agent and styrene are combined to produce the desired product. As d
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## Abstract The use of the reversible addition fragmentation chain transfer—hetero Diels–Alder (RAFT‐HDA) __click__ reaction for the modular construction of block copolymers is extended to the generation of high molecular weight materials. Cyclopentadienyl end‐functionalized polystyrene (PS‐Cp) pre