An efficient reagent for synthesis of α,β-unsaturated aldehydes 3-methylthio-2-propenyl p-tolyl sulfone

Highly efficient and stereoselective acc

Highly efficient and stereoselective access to (Z)-α,β-difluoroallyl alcohols and (Z)-α-fluoro-α,β-unsaturated aldehydes based on the reaction of 2,3,3-trifluoro-1-propenyl p-chlorobenzenesulfonate with Grignard reagents

✍ Kazumasa Funabiki; Yoshitaka Fukushima; Tomomi Inagaki; Eiji Murata; Masaki Mats 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 254 KB

2,3,3-Trifluoro-l-pmpenyl p-chlorobenzenesulfonate (1), readily available from 2,2,3,3tetrafluoropmpanol, reacted smoothly with various Grignard reagents at 50 °(3 to afford the corresponding (Z)-a, fl-difluoroallyl alcohols 2 in moderate to excellent yields. These alcohols were smoothly hydrolyzed

ChemInform Abstract: Highly Efficient an

ChemInform Abstract: Highly Efficient and Stereoselective Access to (Z)-α,β-Difluoroallyl Alcohols and (Z)-α-Fluoro-α,β-unsaturated Aldehydes Based on the Reaction of 2,3,3-Trifluoro-1-propenyl p-Chlorobenzenesulfonate with Grignard Reagents.

✍ K. FUNABIKI; Y. FUKUSHIMA; T. INAGAKI; E. MURATA; M. MATSUI; K. SHIBATA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 1 views

ChemInform Abstract: P(RNCH2CH2)3N: An E

ChemInform Abstract: P(RNCH2CH2)3N: An Efficient Promoter for the Direct Synthesis of E-α,β-Unsaturated Esters.

✍ Philip Kisanga; Bosco D'Sa; John Verkade 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Rh(I)-Catalyzed Three-Component Reaction

Rh(I)-Catalyzed Three-Component Reaction of 2,3-Allenoates, Organoboronic Acids, and Aldehydes. An Efficient Synthesis of α,β-Unsaturated δ-Lactones.

✍ Tao Bai; Shengming Ma; Guochen Jia 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 21 KB 👁 2 views

Efficient Ruthenium-Catalysed Synthesis

Efficient Ruthenium-Catalysed Synthesis of 3-Hydroxy-1-propen-1-yl Benzoates: En Route to an Improved Isomerization of 2-Propyn-1-ols into α,β-Unsaturated Aldehydes

✍ Michel Picquet; Aranzazu Fernández; Christian Bruneau; Pierre H. Dixneuf 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 352 KB 👁 1 views

ChemInform Abstract: Efficient Ruthenium

ChemInform Abstract: Efficient Ruthenium-Catalyzed Synthesis of 3-Hydroxy-1-propen-1-yl Benzoates: En Route to an Improved Isomerization of 2-Propyn-1-ols into α,β-Unsaturated Aldehydes.

✍ Michel Picquet; Aranzazu Fernandez; Christian Bruneau; Pierre H. Dixneuf 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 41 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v