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An efficient preparation of new homoallylamines and α-aminonitriles bearing furyl and thienyl rings

✍ Scribed by Leonor Y. Vargas Méndez; Vladimir V. Kouznetsov

Book ID
102341253
Publisher
Journal of Heterocyclic Chemistry
Year
2008
Tongue
English
Weight
213 KB
Volume
45
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

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New diverse N‐aryl‐N‐[1‐furyl(thienyl)but‐3‐enyl]amines (homoallylamines) or 2‐(N‐arylmethylamino)‐2‐furyl(thienyl)acetonitriles (α‐aminonitriles) were easily prepared in good to excellent yields by an indium‐mediated Barbier‐type reaction between N‐hetarylaldimines and allyl bromide in MeOH or a direct three component reaction between anilines, hetaryl aldehydes and trimethylsilyl cyanide in the presence of a catalytic amount of molecular iodine at room temperature, respectively. The entire set of amines was characterized by IR, ^1^H and ^13^C NMR spectroscopy.

📜 SIMILAR VOLUMES

ChemInform Abstract: An Efficient Prepar
ChemInform Abstract: An Efficient Preparation of New Homoallylamines and α-Aminonitriles Bearing Furyl and Thienyl Rings.
✍ Leonor Y. Vargas Mendez; Vladimir V. Kouznetsov 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 28 KB

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