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An Efficient Palladium-Catalyzed Synthesis of Cinnamaldehydes from Acrolein Diethyl Acetal and Aryl Iodides and Bromides

✍ Scribed by Battistuzzi, Gianfranco; Cacchi, Sandro; Fabrizi, Giancarlo

Book ID
120626964
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
70 KB
Volume
5
Category
Article
ISSN
1523-7060

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Efficient Heterogeneously Palladium-Cata
Efficient Heterogeneously Palladium-Catalysed Heck Arylation of Acrolein Diethyl Acetal. Selective Synthesis of Cinnamaldehydes or 3-Arylpropionic Esters
✍ SΓ©bastien NoΓ«l; Ciahong Luo; Catherine Pinel; Laurent Djakovitch πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 543 KB

## Abstract A heterogeneous tetrakis(ammine)palladium‐NaY zeolite {[Pd(NH~3~)~4~]/NaY} catalyst was applied successfully to the Heck arylation of acrolein diethyl acetal using a large variety of aryl and heteroaryl bromides. Depending on the reaction conditions (Heck __versus__ Cacchi) good to high