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An efficient oxidative cleavage of carbon-silicon bonds by a dioxygen/hydroquinone system

โœ Scribed by Kohei Tamao; Takashi Hayashi; Yoshihiko Ito


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
250 KB
Volume
30
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Carbon silicon bond cleavage in the oxid
โœ Enrico Baciocchi; Tiziana Del Giacco; Cesare Rol; Giovanni Vittorio Sebastiani ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

Benzyltrirrethylsilanes react with cerium(IV) ammonium nitrate in AcOH to give products -of C-Si cleavage (benzyl nitrate and acetate), under very mild conditions and in quantitative yields. The reaction rate is very sensitive to the nature of the ring substituents (y= -5.4), which clearly suggests