Carbon silicon bond cleavage in the oxid
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Enrico Baciocchi; Tiziana Del Giacco; Cesare Rol; Giovanni Vittorio Sebastiani
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Article
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1989
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Elsevier Science
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French
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Benzyltrirrethylsilanes react with cerium(IV) ammonium nitrate in AcOH to give products -of C-Si cleavage (benzyl nitrate and acetate), under very mild conditions and in quantitative yields. The reaction rate is very sensitive to the nature of the ring substituents (y= -5.4), which clearly suggests