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AN EFFICIENT OXIDATION OF LONG CHAIN ALKYL METHYL SULFIDES TO SULFOXIDES

โœ Scribed by Yamamoto, Tamotsu; Hayakawa, Tetsushi; Yoshino, Mugi; Hata, Soh-Ichiroh; Hirayama, Yorinobu

Book ID
125477063
Publisher
Taylor and Francis Group
Year
2000
Tongue
English
Weight
268 KB
Volume
32
Category
Article
ISSN
0030-4948

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๐Ÿ“œ SIMILAR VOLUMES

An efficient asymmetric oxidation of sul
An efficient asymmetric oxidation of sulfides to sulfoxides
โœ Philippe Pitchen; Henri B. Kagan ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 240 KB

The Sharpless reagent (Ti(OiPr)4 t 1 mol eq. diethyl tartrate (DET) t 2 J-BuOOH) modified by addition of one mol eq. H20 gives a new homogeneous reagent which cleanly oxidizes sulfidesinto sulfoxides in dichloromethane. The best results were obtained for the stoichiometry Ti/DET/ H20/J-BuOOH = 1:2:1