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An efficient method for the trimethylsilylation of tertiary alcohols

✍ Scribed by R. G. Visser; H. J. T. Bos; L. Brandsma

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 112 KB
Volume: 99
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19800990210

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✦ Synopsis

Abstract

Tertiary acetylenic alcohols have been transformed into the O‐trimethylsilyl derivatives with trimethylsilyl chloride and triethylamine, using catalytic amounts of dimethyl sulfoxide, hexamethylphosphoric triamide, imidazole, or 1,5‐diazabicyclo[5.4.0]undec‐5‐ene. Saturated tertiary alcohols can be trimethylsilylated in the same way.

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