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An efficient method for the preparation of benzylγ-ketohexanoates

✍ Scribed by Iqbal, Muhammad; Baloch, Imam B.; Baloch, Musa K.

Book ID
119932394
Publisher
Versita
Year
2013
Tongue
English
Weight
256 KB
Volume
67
Category
Article
ISSN
0366-6352

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✦ Synopsis

Abstract

Twenty acid chlorides, 4-(mono/di-benzyloxy)-4-ketobutanoyl chlorides (Ia–XXa) were synthesised by the reaction of monoesters of succinic acid with thionyl chloride. The product thus obtained (4-benzyloxy-4-ketobutanoyl chlorides) was treated with diethylcadmium to convert it into the corresponding keto-esters (Ib–XXb), the mono/di-benzyl-γ-ketohexanoates, with a good yield. All the compounds thus prepared were characterised by physical, spectroscopic (UV-VIS, IR, 1H NMR, 13C NMR), and mass measurements techniques.

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