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An efficient electrochemical synthesis of diamino-o-benzoquinone: Mechanistic and kinetic evaluation of the reaction of azide ion with o-benzoquinone

✍ Scribed by Nematollahi, Davood ;Afkhami, Abbas ;Tammari, Esmail ;Shariatmanesh, Tahere ;Hesari, Mahdi ;Shojaeifard, Maryam

Book ID
120616142
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
339 KB
Volume
2
Category
Article
ISSN
1359-7345

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✦ Synopsis

An efficient method for the synthesis of diamino-o-benzoquinone based on the Michael reaction of electrochemically generated o-benzoquinone with azide ion is described, as well as an estimation of the homogeneous rate constant (k(obs)) of the reaction of o-benzoquinone with azide ion by the digital-simulation method.

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